Electrosynthesis and properties of poly(3,4-ethylenedioxythiophene) films functionalized with titanocene dichloride complex
Identifieur interne : 008C89 ( Main/Repository ); précédent : 008C88; suivant : 008C90Electrosynthesis and properties of poly(3,4-ethylenedioxythiophene) films functionalized with titanocene dichloride complex
Auteurs : RBID : Pascal:06-0200229Descripteurs français
- Pascal (Inist)
- Etude expérimentale, Interface électrode électrolyte, Polymérisation électrolytique, Dépôt électrolytique, Polymère hétérocyclique, Polymère conducteur, Thiophène dérivé polymère, Métallocène, Electrode ITO, Electrode disque, Platine, Solvant organique, Structure surface, Propriété électrochimique, Activité électrochimique, Potentiel oxydoréduction, Microscopie tunnel balayage, Voltammétrie cyclique, Ethylènedioxythiophène polymère, Titanocène complexe.
- Wicri :
- concept : Platine.
English descriptors
- KwdEn :
- Conducting polymers, Cyclic voltammetry, Disk electrode, Electrochemical activity, Electrochemical polymerization, Electrochemical properties, Electrode electrolyte interface, Electrodeposition, Experimental study, Heterocyclic polymer, Indium tin oxide electrode, Metallocene, Organic solvent, Platinum, Redox potential, Scanning tunneling microscopy, Surface structure, Thiophene derivative polymer.
Abstract
Synthesis of a titanocene dichloride derivative functionalized with 3,4-etylenedioxythiophene group, TclEDOT (Cl2TiCpC5H4(CH2) (3,4-ethylenedioxythiophene)) has been described. Redox behavior of the monomer in tetrahydrofuran (THF), dichloromethane (DCM) and acetonitrile (AN) at different scan rates has been discussed in terms of different ability of these solvents to coordination with the reduced titanocene (Tc) complex and the solvation of Cl- anions. Electrooxidation of TclEDOT to get a conducting polymer film with immobilized titanocene dichloride centers and electrochemical properties of its polymer matrix in background acetonitrile solution have been compared with those of non-substituted PEDOT and PEDOT-methanol derivative (PEDOTMet), to elucidate the effect of substituents both on polymerization and redox potentials of the matrix. STM and AFM images of p(TclEDOT) films obtained with potentiodynamic and potentiostatic regimes are compared to illustrate that the films deposited at constant potential are better ordered and more compact than those obtained by cyclic voltammetry. A comparison of the cyclic voltammograms of p(Tc1EDOT) and poly(titanocene-propyl-pyrrole) (p(Tc3Py)) films in 0.1 TBAPF6 in THF has shown that the electroactivity of the polymer matrix of p(TclEDOT) is extended to more negative potentials in comparison to that of p(Tc3Py). This results in the anodic shift of redox potential of Tc centers immobilized in p(Tc 1EDOT) film with respect to that of the centers fixed in p(Tc3Py).
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Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Bourgogne</region></placeName><orgName type="university">Université de Bourgogne</orgName></affiliation></author><author><name sortKey="Refczynska, Monika" uniqKey="Refczynska M">Monika Refczynska</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Warsaw University, ul. Pasteura 1</s1><s2>Warsaw 02 093</s2><s3>POL</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Pologne</country><wicri:noRegion>Warsaw 02 093</wicri:noRegion></affiliation></author><author><name sortKey="Goux, Jerome" uniqKey="Goux J">Jerome Goux</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LSEO-UMR 5188 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Bourgogne</region></placeName><orgName type="university">Université de Bourgogne</orgName></affiliation></author><author><name sortKey="Lesniewska, Eric" uniqKey="Lesniewska E">Eric Lesniewska</name><affiliation wicri:level="4"><inist:fA14 i1="03"><s1>LPUB-UMR 5025 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>5 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Bourgogne</region></placeName><orgName type="university">Université de Bourgogne</orgName></affiliation></author><author><name sortKey="Boni, Gilles" uniqKey="Boni G">Gilles Boni</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LSEO-UMR 5188 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Bourgogne</region></placeName><orgName type="university">Université de Bourgogne</orgName></affiliation></author><author><name sortKey="Moise, Claude" uniqKey="Moise C">Claude Moise</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LSEO-UMR 5188 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Bourgogne</region></placeName><orgName type="university">Université de Bourgogne</orgName></affiliation></author></titleStmt><publicationStmt><idno type="inist">06-0200229</idno><date when="2006">2006</date><idno type="stanalyst">PASCAL 06-0200229 INIST</idno><idno type="RBID">Pascal:06-0200229</idno><idno type="wicri:Area/Main/Corpus">009197</idno><idno type="wicri:Area/Main/Repository">008C89</idno></publicationStmt><seriesStmt><idno type="ISSN">0013-4686</idno><title level="j" type="abbreviated">Electrochim. acta</title><title level="j" type="main">Electrochimica acta</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Conducting polymers</term><term>Cyclic voltammetry</term><term>Disk electrode</term><term>Electrochemical activity</term><term>Electrochemical polymerization</term><term>Electrochemical properties</term><term>Electrode electrolyte interface</term><term>Electrodeposition</term><term>Experimental study</term><term>Heterocyclic polymer</term><term>Indium tin oxide electrode</term><term>Metallocene</term><term>Organic solvent</term><term>Platinum</term><term>Redox potential</term><term>Scanning tunneling microscopy</term><term>Surface structure</term><term>Thiophene derivative polymer</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>Interface électrode électrolyte</term><term>Polymérisation électrolytique</term><term>Dépôt électrolytique</term><term>Polymère hétérocyclique</term><term>Polymère conducteur</term><term>Thiophène dérivé polymère</term><term>Métallocène</term><term>Electrode ITO</term><term>Electrode disque</term><term>Platine</term><term>Solvant organique</term><term>Structure surface</term><term>Propriété électrochimique</term><term>Activité électrochimique</term><term>Potentiel oxydoréduction</term><term>Microscopie tunnel balayage</term><term>Voltammétrie cyclique</term><term>Ethylènedioxythiophène polymère</term><term>Titanocène complexe</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Platine</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Synthesis of a titanocene dichloride derivative functionalized with 3,4-etylenedioxythiophene group, TclEDOT (Cl<sub>2</sub>TiCpC<sub>5</sub>H<sub>4</sub>(CH<sub>2</sub>) (3,4-ethylenedioxythiophene)) has been described. Redox behavior of the monomer in tetrahydrofuran (THF), dichloromethane (DCM) and acetonitrile (AN) at different scan rates has been discussed in terms of different ability of these solvents to coordination with the reduced titanocene (Tc) complex and the solvation of Cl<sup>-</sup> anions. Electrooxidation of TclEDOT to get a conducting polymer film with immobilized titanocene dichloride centers and electrochemical properties of its polymer matrix in background acetonitrile solution have been compared with those of non-substituted PEDOT and PEDOT-methanol derivative (PEDOTMet), to elucidate the effect of substituents both on polymerization and redox potentials of the matrix. STM and AFM images of p(TclEDOT) films obtained with potentiodynamic and potentiostatic regimes are compared to illustrate that the films deposited at constant potential are better ordered and more compact than those obtained by cyclic voltammetry. A comparison of the cyclic voltammograms of p(Tc1EDOT) and poly(titanocene-propyl-pyrrole) (p(Tc3Py)) films in 0.1 TBAPF<sub>6</sub> in THF has shown that the electroactivity of the polymer matrix of p(TclEDOT) is extended to more negative potentials in comparison to that of p(Tc3Py). This results in the anodic shift of redox potential of Tc centers immobilized in p(Tc 1EDOT) film with respect to that of the centers fixed in p(Tc3Py).</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0013-4686</s0></fA01><fA02 i1="01"><s0>ELCAAV</s0></fA02><fA03 i2="1"><s0>Electrochim. acta</s0></fA03><fA05><s2>51</s2></fA05><fA06><s2>11</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Electrosynthesis and properties of poly(3,4-ethylenedioxythiophene) films functionalized with titanocene dichloride complex</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>Electrode processes: Selection of papers from the International Conference, 15-18 September 2004, Szczyrk, Poland</s1></fA09><fA11 i1="01" i2="1"><s1>SKOMPSKA (Magdalena)</s1></fA11><fA11 i1="02" i2="1"><s1>VOROTYNTSEV (Mikhail A.)</s1></fA11><fA11 i1="03" i2="1"><s1>REFCZYNSKA (Monika)</s1></fA11><fA11 i1="04" i2="1"><s1>GOUX (Jerome)</s1></fA11><fA11 i1="05" i2="1"><s1>LESNIEWSKA (Eric)</s1></fA11><fA11 i1="06" i2="1"><s1>BONI (Gilles)</s1></fA11><fA11 i1="07" i2="1"><s1>MOISE (Claude)</s1></fA11><fA12 i1="01" i2="1"><s1>KULESZA (Pawel)</s1><s9>ed.</s9></fA12><fA12 i1="02" i2="1"><s1>LIPKOWSKI (Jacek)</s1><s9>ed.</s9></fA12><fA14 i1="01"><s1>Department of Chemistry, Warsaw University, ul. Pasteura 1</s1><s2>Warsaw 02 093</s2><s3>POL</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>LSEO-UMR 5188 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ><sZ>6 aut.</sZ><sZ>7 aut.</sZ></fA14><fA14 i1="03"><s1>LPUB-UMR 5025 CNRS-Université de Bourgogne, Mirande, 9 Avenue A. Savary, BP 47 870</s1><s2>Dijon 21078</s2><s3>FRA</s3><sZ>5 aut.</sZ></fA14><fA15 i1="01"><s1>Department of Chemistry, University of Warsaw</s1><s2>02-093 Warsaw</s2><s3>POL</s3><sZ>1 aut.</sZ></fA15><fA15 i1="02"><s1>Department of Chemistry and Biochemistry, University of Guelph</s1><s2>Guelph, ON N1G 2W1</s2><s3>CAN</s3><sZ>2 aut.</sZ></fA15><fA18 i1="01" i2="1"><s1>University of Warsaw. Department of Chemistry</s1><s2>Warsaw</s2><s3>POL</s3><s9>org-cong.</s9></fA18><fA18 i1="02" i2="1"><s1>Polish Chemical Society. Electrochemical Section</s1><s2>00-227 Warsaw</s2><s3>POL</s3><s9>org-cong.</s9></fA18><fA18 i1="03" i2="1"><s1>Polish Academy of Sciences. Committee of Analytical Chemistry. Electroanalytical Commission</s1><s2>Warsaw</s2><s3>POL</s3><s9>org-cong.</s9></fA18><fA18 i1="04" i2="1"><s1>International Society of Electrochemistry (ISE). Electroanalytical Chemistry Division</s1><s2>1004 Lausanne</s2><s3>CHE</s3><s9>org-cong.</s9></fA18><fA18 i1="05" i2="1"><s1>Electrochemical Society (ECS). European Section</s1><s2>Pennington, NJ</s2><s3>USA</s3><s9>org-cong.</s9></fA18><fA18 i1="06" i2="1"><s1>Kosciuszko Foundation</s1><s2>New York, NY</s2><s3>USA</s3><s9>org-cong.</s9></fA18><fA20><s1>2108-2119</s1></fA20><fA21><s1>2006</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>1516</s2><s5>354000115209140010</s5></fA43><fA44><s0>0000</s0><s1>© 2006 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>23 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>06-0200229</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Electrochimica acta</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>Synthesis of a titanocene dichloride derivative functionalized with 3,4-etylenedioxythiophene group, TclEDOT (Cl<sub>2</sub>TiCpC<sub>5</sub>H<sub>4</sub>(CH<sub>2</sub>) (3,4-ethylenedioxythiophene)) has been described. Redox behavior of the monomer in tetrahydrofuran (THF), dichloromethane (DCM) and acetonitrile (AN) at different scan rates has been discussed in terms of different ability of these solvents to coordination with the reduced titanocene (Tc) complex and the solvation of Cl<sup>-</sup> anions. Electrooxidation of TclEDOT to get a conducting polymer film with immobilized titanocene dichloride centers and electrochemical properties of its polymer matrix in background acetonitrile solution have been compared with those of non-substituted PEDOT and PEDOT-methanol derivative (PEDOTMet), to elucidate the effect of substituents both on polymerization and redox potentials of the matrix. STM and AFM images of p(TclEDOT) films obtained with potentiodynamic and potentiostatic regimes are compared to illustrate that the films deposited at constant potential are better ordered and more compact than those obtained by cyclic voltammetry. A comparison of the cyclic voltammograms of p(Tc1EDOT) and poly(titanocene-propyl-pyrrole) (p(Tc3Py)) films in 0.1 TBAPF<sub>6</sub> in THF has shown that the electroactivity of the polymer matrix of p(TclEDOT) is extended to more negative potentials in comparison to that of p(Tc3Py). This results in the anodic shift of redox potential of Tc centers immobilized in p(Tc 1EDOT) film with respect to that of the centers fixed in p(Tc3Py).</s0></fC01><fC02 i1="01" i2="X"><s0>001C01H04A</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Interface électrode électrolyte</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Electrode electrolyte interface</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Interfase electrodo electrolito</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Polymérisation électrolytique</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Electrochemical polymerization</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Polimerización electrolítica</s0><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Dépôt 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l="FRE"><s0>Structure surface</s0><s5>15</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Surface structure</s0><s5>15</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Estructura superficie</s0><s5>15</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Propriété électrochimique</s0><s5>16</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Electrochemical properties</s0><s5>16</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Propiedad electroquímica</s0><s5>16</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Activité électrochimique</s0><s5>17</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Electrochemical activity</s0><s5>17</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Actividad electroquímica</s0><s5>17</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Potentiel oxydoréduction</s0><s5>18</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Redox potential</s0><s5>18</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Potencial redox</s0><s5>18</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Microscopie tunnel balayage</s0><s5>19</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Scanning tunneling microscopy</s0><s5>19</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Microscopía túnel barrido</s0><s5>19</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Voltammétrie cyclique</s0><s5>20</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Cyclic voltammetry</s0><s5>20</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Voltametría cíclica</s0><s5>20</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Ethylènedioxythiophène polymère</s0><s2>NK</s2><s4>INC</s4><s5>32</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Titanocène complexe</s0><s2>NK</s2><s4>INC</s4><s5>34</s5></fC03><fC07 i1="01" i2="X" l="FRE"><s0>Titane Composé organique</s0><s2>NC</s2><s2>NA</s2><s5>08</s5></fC07><fC07 i1="01" i2="X" l="ENG"><s0>Titanium Organic compounds</s0><s2>NC</s2><s2>NA</s2><s5>08</s5></fC07><fC07 i1="01" i2="X" l="SPA"><s0>Titanio Compuesto orgánico</s0><s2>NC</s2><s2>NA</s2><s5>08</s5></fC07><fC07 i1="02" i2="X" l="FRE"><s0>Métal transition</s0><s2>NC</s2><s5>12</s5></fC07><fC07 i1="02" i2="X" l="ENG"><s0>Transition metal</s0><s2>NC</s2><s5>12</s5></fC07><fC07 i1="02" i2="X" l="SPA"><s0>Metal transición</s0><s2>NC</s2><s5>12</s5></fC07><fN21><s1>128</s1></fN21><fN44 i1="01"><s1>PSI</s1></fN44><fN82><s1>PSI</s1></fN82></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>International Conference on Electrode Processes</s1><s3>Szczyrk POL</s3><s4>2004-09-15</s4></fA30></pR></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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